Chemically strengthened glass

Chemically strengthened glass is a type of glass that has increased strength as a result of a post-production chemical process. Chemical strengthening is the name given to glass products that have been strengthened by means of an ion-exchange process. It is a surface treatment which occurs at a temperature lower than glass melting temperature. The process is particularly useful for thin glass, tiny glass and shape glass which cannot be tempered by ordinary physical tempering.

Chemically strengthened glass is typically six to eight times the strength of float glass. In the case of breakage, chemically strengthened glass breaks into bigger pieces which are not as sharp as those of non-toughened glass. The surface compression condition which is higher in the case of a chemically strengthened glass also involves an increase of flexion resistance, which is one of the main characteristics of chemically strengthened glass.

Chemical strengthening results in a strengthening similar to toughened glass. Chemically strengthened glass has little or no bow or warp, optical distortion or strain pattern. This differs from toughened glass, in which slender pieces can be significantly bowed.

Chemically strengthened glass may be cut after strengthening, but loses its added strength within the region of approximately 20 mm of the cut. Similarly, when the surface of chemically strengthened glass is deeply scratched, this area loses its additional strength. Chemically strengthened glass retains its colour and light transmission properties after treatment.

Chemically strengthened glass offers an improved scratching, impact and bending strength, as well as an increased temperature stability.

Manufacturing process

The glass is chemically strengthened by a surface finishing process. The glass to be treated is dipped into a bath of dissolved potassium salts at a temperature about 380oC for duration from 4 to 30 hours, producing an ionic exchange between the superficial sodium ions in the glass and potassium ions inside the bath. The cycle time would be greatly reduced if the glass is made of certain elements such as lithium or magnesium because ion mobility between potassium and these elements is a lot faster. The process parameters such as ion exchanging time and temperature would be modified according to the type of glass to be treated and the required strengthen specification.

The introduction of potassium ions which are larger in size than the sodium ions results in the establishment of a system of residual stress characterized by compression stretches on the surface counterbalanced by traction stretches within the glass

Sodium ions and thus, creates stress on glass surface. During cooling, the potassium on surface shrinks little while the sodium in inner shrinks larger. Hence, stress is induced between glass surface and inside and consequently, the glass is strengthened.

Advanced process

There also exists a more advanced two-stage process for making chemically strengthened glass, in which the glass article is first immersed in a sodium nitrate bath at 450 °C, which enriches the surface with sodium ions. This leaves more sodium ions on the glass for the immersion in potassium nitrate to replace with potassium ions. In this way, the use of a sodium nitrate bath increases the potential for surface compression in the finished article.

Classifications

Chemical strengthened glass is classified by two strength components: surface compression and depth of layer (DOL). Surface compression values relate to flexural (bending) strength (MOR), impact strength, hardness penetration (scratching) and thermal shock resistance. Depth of layer values relate primarily to the amount of sustained abrasion resistance and the impact resistance of the surface compression layer.

Applications

Chemically strengthened glass was used for the aircraft canopy of some fighter aircraft. The chemically treated glass boasts a transparency range from the UV through the visible and into the infrared. This permits weapons systems designers to operate guidance devices whether they are CCD, radio frequency, infrared or laser based. The material's proponents stress that chemically treated glass is not just for use in military applications.

It can be used in numerous applications that demand toughness and optical clarity. The material is also useful for viewports, protective covers, and front surface optics in hostile environments whose elements may include high temperature, high pressure and vacuum conditions. Less demanding applications include point of sale scanner windows used in grocery store and retail scanners.

Bullet Proof Glass

Bullet proof glass or bullet resistant glass refers to any type of glass that is built to stand up against being penetrated by bullets. Although the public uses the term ‘bullet proof glass’, generally within the industry itself it is referred to as bullet-resistant glass, because there is no feasible way to create consumer-level glass that can truly be proof against bullets.

Bullet proof glass is usually constructed using a strong but transparent material such as polycarbonate thermoplastic or by using layers of laminated glass. The desired result is a material with an appearance and light-transmitting behavior of standard glass but offers varying degrees of protection from small arms fire.

The polycarbonate layer, usually consisting of products such as Armormax, Makroclear, Cyrolon, Lexan or Tuffak, is often sandwiched between layers of regular glass. The use of plastic in the laminate provides impact-resistance, such as physical assault with a hammer, an axe, etc. The plastic provides little in the way of bullet-resistance. The glass, which is much harder than plastic, flattens the bullet and thereby prevents penetration. This type of bullet proof glass is usually 70–75 mm (2.8–3.0 in) thick.

Bullet proof glass constructed of laminated glass layers is built from glass sheets bonded together with polyvinyl butyral, polyurethane or ethylene-vinyl acetate. This type of bullet proof glass has been in regular use on combat vehicles since World War II; it is typically about 100–120 mm (3.9–4.7 in) thick and is usually extremely heavy.

Working Principle of the Bullet Resistant Glass

In the bullet proof glass, the Laminate-layers of tough plastic called polycarbonate sandwiched in between the pieces of toughened glass make the glass ten times thicker than the ordinary glass and it is very heavy. If someone fires a bullet at an ordinary piece of glass, the glass can't bend and absorb the energy. So the glass shatters and the bullet carries on through with hardly any loss of momentum. That's why ordinary glass offers no protection against bullets.

But when a bullet strikes bullet proof glass, its energy spreads out sideways through the layers. Because the energy is divided between a number of different pieces of glass and plastic, and spread over a large area, it is quickly absorbed. The bullet slows down so much that it no longer has enough energy to pierce through—or to do much damage if it does so. Although the glass panes do break, the plastic layers stop them flying apart.

Advances in bullet resistant glass have led to the invention of one-way bullet resistant glass, such as used in some bank armored cars. This glass will resist incoming small arms fire striking the outside of the glass, but will allow those on the other side of the glass, such as guards firing from inside the armored car, to fire through the glass at the exterior threat.

One-way Bullet Proof Glass

One-way bullet proof glass is usually made up of two layers, a brittle layer on the outside and a flexible one on the inside. When a bullet is fired from the outside it hits the brittle layer first, shattering an area of it. This shattering absorbs some of the bullet's kinetic energy, and spreads it on a larger area. When the slowed bullet hits the flexible layer, it is stopped. However, when a bullet is fired from the inside, it hits the flexible layer first. The bullet penetrates the flexible layer because its energy is focused on a smaller area; the brittle layer then shatters outward due to the flexing of the inner layer and does not hinder the bullet's progress.

Advancement

The field of bullet proof glass is constantly developing, and there are a number of military projects underway to create lighter-weight, more defensive forms of bullet proof glass. One of the most promising is the use of aluminum oxynitride in the outer layer, in place of a polymer layer.

U.S. military researchers are moving quickly to develop this new class of transparent armour incorporating aluminium oxynitride (Trade name: ALON) as the outside "strike plate" layer. It performs much better than traditional glass/polymer laminates. Aluminium oxynitride "glass" can't defeat threats like the .50 caliber armor piercing rounds using material that is not prohibitively heavy. This more resistant-glass that can be used in military assault vehicles and aircraft.

Applications

Bullet Resistant glasses have a wide range of applications as follows:

• Banks
• Government Buildings
• Convenience Stores
• Churches
• Schools
• Check Cashing Stores
• Liquor Stores
• Post Offices
• Jewelry Stores
• Art Galleries